I can confirm for SF 625x/626x .. and in mpd is no subtitle
(and mpd url contain always “subtitle_language:unused”)
So I can only offer the manual method:
Open DevTools in your Browser (F12), click on Network and filter: vtt
Now play (or reload) your title, so you should see a vtt URL at the left.

Open url with rightclick in new tab or dl with your default Downloader